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Undecacarbonyl(methylcyclopentadienyl)- tetrahedro -triiridiummolybdenum, undecacarbonyl(tetramethylcyclopentadienyl)- tetrahedro -triiridiummolybdenum and undecacarbonyl(pentamethylcyclopentadienyl)- tetrahedro -triiridiummolybdenum

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Lucas, Nigel; Whittall, Ian; Humphrey, Mark

Description

The crystal structure of the molybdenum organometallic compound complexes was studied. The alkyl cyclopentadienyl ligands provided flexibility in tuning the electronic and steric properties of the complex. The decreasing Mo-Co distances on increasing both steric bulk and electronic-donating properties of the alkylcyclopentadienyl ligands showed that electronic factors dominated over steric consideration of the ligand disposition.

dc.contributor.authorLucas, Nigel
dc.contributor.authorWhittall, Ian
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-13T22:25:43Z
dc.date.available2015-12-13T22:25:43Z
dc.identifier.issn0108-2701
dc.identifier.urihttp://hdl.handle.net/1885/73386
dc.description.abstractThe crystal structure of the molybdenum organometallic compound complexes was studied. The alkyl cyclopentadienyl ligands provided flexibility in tuning the electronic and steric properties of the complex. The decreasing Mo-Co distances on increasing both steric bulk and electronic-donating properties of the alkylcyclopentadienyl ligands showed that electronic factors dominated over steric consideration of the ligand disposition.
dc.publisherMunksgaard International Publishers
dc.sourceActa Crystallographica Section C: Crystal Structure Communications
dc.subjectKeywords: Chemical bonds; Complexation; Crystal structure; Molybdenum compounds; Tuning; Ligand disposition; Organometallics
dc.titleUndecacarbonyl(methylcyclopentadienyl)- tetrahedro -triiridiummolybdenum, undecacarbonyl(tetramethylcyclopentadienyl)- tetrahedro -triiridiummolybdenum and undecacarbonyl(pentamethylcyclopentadienyl)- tetrahedro -triiridiummolybdenum
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolumeC58
dc.date.issued2002
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub3669
local.type.statusPublished Version
local.contributor.affiliationLucas, Nigel, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWhittall, Ian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpagem249
local.bibliographicCitation.lastpagem251
local.identifier.doi10.1107/S0108270101020558
dc.date.updated2015-12-11T08:17:59Z
local.identifier.scopusID2-s2.0-0036528957
CollectionsANU Research Publications

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