A chemoenzymatic synthesis of differentially protected D-talose derivatives
Banwell, Martin; Edwards, Alison; Lambert, John N; Ma, Xinghua; Watson, Keith G
Description
The synthesis of the D-talose derivatives from the readily available and enantiomerically pure cis-1,2-dihydrocatechol was discussed. The synthesis included a stannylene acetal-mediated epimerization process. The dehydroxylation of D-galactal provided a different route to target. The triacetates were chemically correlated with known derivatives of D-talose. A mixture of these compounds was also subjected to reaction with aqueous trifluoroacetic acid to affect global deprotection and generate...[Show more]
Collections | ANU Research Publications |
---|---|
Date published: | 2002 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/73004 |
Source: | Australian Journal of Chemistry |
Download
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.
Updated: 17 November 2022/ Responsible Officer: University Librarian/ Page Contact: Library Systems & Web Coordinator