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A chemoenzymatic synthesis of differentially protected D-talose derivatives

Banwell, Martin; Edwards, Alison; Lambert, John N; Ma, Xinghua; Watson, Keith G

Description

The synthesis of the D-talose derivatives from the readily available and enantiomerically pure cis-1,2-dihydrocatechol was discussed. The synthesis included a stannylene acetal-mediated epimerization process. The dehydroxylation of D-galactal provided a different route to target. The triacetates were chemically correlated with known derivatives of D-talose. A mixture of these compounds was also subjected to reaction with aqueous trifluoroacetic acid to affect global deprotection and generate...[Show more]

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
URI: http://hdl.handle.net/1885/73004
Source: Australian Journal of Chemistry

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