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A chemoenzymatic synthesis of the 12-membered macrolide (-)-cladospolide A

Banwell, Martin; Jolliffe, Katrina; Loong, David; McRae, Kenneth; Vounatsos, Filisaty


The enantiomerically pure cis-1,2-dihydrocatechol 7, which is obtained by microbial oxidation of chlorobenzene, has been converted, via a sequence of reactions including ring-closing metathesis and Yamaguchi lactonisation steps, into the natural product (-)-cladospolide A (1).

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Journal of the Chemical Society, Perkin Transactions 1


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