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Mobile Rings on a Polyrotaxane Lead to a Yield Force

Pinson, Matthew; Sevick, Edith M; Williams, David

Description

We examine the role of mobile rings on the stretching profile of a single polyrotaxane molecule that is tethered in space by fixing one of the rings, the "control ring". We show that the translational entropy of the mobile rings can lead to dramatic chang

dc.contributor.authorPinson, Matthew
dc.contributor.authorSevick, Edith M
dc.contributor.authorWilliams, David
dc.date.accessioned2015-12-13T22:24:39Z
dc.identifier.issn0024-9297
dc.identifier.urihttp://hdl.handle.net/1885/72820
dc.description.abstractWe examine the role of mobile rings on the stretching profile of a single polyrotaxane molecule that is tethered in space by fixing one of the rings, the "control ring". We show that the translational entropy of the mobile rings can lead to dramatic chang
dc.publisherAmerican Chemical Society
dc.sourceMacromolecules
dc.subjectKeywords: Applied forces; Chain extension; Control rings; Polyrotaxanes; Translational entropies; Yield force; Macromolecules; Chemistry
dc.titleMobile Rings on a Polyrotaxane Lead to a Yield Force
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume46
dc.date.issued2013
local.identifier.absfor020405 - Soft Condensed Matter
local.identifier.absfor030704 - Statistical Mechanics in Chemistry
local.identifier.ariespublicationf5625xPUB3442
local.type.statusPublished Version
local.contributor.affiliationPinson, Matthew, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSevick, Edith M, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWilliams, David, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue10
local.bibliographicCitation.startpage4191
local.bibliographicCitation.lastpage4197
local.identifier.doi10.1021/ma4000094
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T09:10:58Z
local.identifier.scopusID2-s2.0-84878296076
local.identifier.thomsonID000319795800054
CollectionsANU Research Publications

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