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Mobile Rings on a Polyrotaxane Lead to a Yield Force

Pinson, Matthew; Sevick, Edith M; Williams, David


We examine the role of mobile rings on the stretching profile of a single polyrotaxane molecule that is tethered in space by fixing one of the rings, the "control ring". We show that the translational entropy of the mobile rings can lead to dramatic chang

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Macromolecules
DOI: 10.1021/ma4000094


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