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Facile reduction of coordinated α-imino acids to amino acids by dithionite and borohydride.

Pearce, Dierdre; Hartshorn, Richard; Sargeson, Alan

Description

Sodium dithionite was found to reduce a range of α-iminoacidato ligands, chelated to cobalt(III), to the related α-aminoacidato species. For the bis(1,2-ethanediamine) system, the distribution of the products showed a small stereoselectivity towards the

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
URI: http://hdl.handle.net/1885/72565
Source: Dalton Transactions

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