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Assembly of polyamines via amino acids from three components using cobalt(III) template methodology.

Laval, Gilles; Clegg, William; Crane, Christopher; Hammershoi, Anders; Sargeson, Alan; Golding, Bernard

Description

A versatile and efficient template synthesis has been developed to synthesise novel polyamines [e.g. rac-N3-(3-aminopropyl)butane-1,3-diamine, isospermidine 1] via amino acids [e.g. (2R,4S/2S,4R)-N4-(3-aminopropyl)-2,4-di-aminopentanoic acid] using cobalt(III) to assemble the three precursor components in a biomimetic manner.

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
URI: http://hdl.handle.net/1885/72562
Source: Chemical Communications
DOI: 10.1039/b206462f

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