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An unusual pendant-arm macrocycle formed by condensation of a cobalt(III) tripodal complex with methanal.

Angus, Patricia; Geue, Rodney; Jensen, Niels; Larsen, Krebs; Qin, Chang; Sargeson, Alan


The reaction of [Co(ten)]3+ {ten = 4,4′,4″-ethylidynetris(3-thiabutan-1-amine)} with methanal and base in acetonitrile or water led to the synthesis of an unusual pendant-arm macrocyclic complex, 8-(4′-ammonio-2′-thiabutyl)-8-methyl-1-oxa-6, 10-di

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Dalton Transactions


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