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Rhodium-catalyzed hydroformylation of 4-vinylpyridine: 4-ethylpyridine formation via an unusual cleavage of the Rh?C bond by the enolic form of the oxo product.

Lazzaroni, Raffaello; Settambolo, Roberta; Caiazzo, Aldo; Bennett, Martin

Description

The hydroformylation of 4-vinylpyridine (4VP) with rhodium catalyst Rh4(CO)12 modified with phosphine ligands (PMe2Ph) is not completely chemoselective to the branched aldehyde 2-(4-pyridyl)propanal (4α), the corresponding hydrogenation product 4-ethylpy

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
URI: http://hdl.handle.net/1885/72536
Source: Organometallics
DOI: 10.1021/om0105371

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