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Preparation and reactivity of mononuclear platinum(0) complexes containing a η 2 -coordinated alkynylphosphine.

Bennett, Martin; Kwan, Laurence; Rae, A David; Wenger, Eric; Willis, Anthony


Displacement of ethene from [Pt(η2-C2H4)(dcpe)] by Ph2PC≡CMe gives the monomeric η2-alkynylphosphine complex [Pt(η2-Ph2PC≡CMe)(dcpe)] (5). Reaction of 5 with one equivalent of HCl forms, in benzene, the four-coordinate η1-vinyl-platinum(II) comple

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Dalton Transactions


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