Preparation and reactivity of mononuclear platinum(0) complexes containing a η 2 -coordinated alkynylphosphine.
Displacement of ethene from [Pt(η2-C2H4)(dcpe)] by Ph2PC≡CMe gives the monomeric η2-alkynylphosphine complex [Pt(η2-Ph2PC≡CMe)(dcpe)] (5). Reaction of 5 with one equivalent of HCl forms, in benzene, the four-coordinate η1-vinyl-platinum(II) comple
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