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A fresh approach to voltammetric modelling.

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Mahon, Peter; Myland, Jan; Oldham, Keith

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A modular semianalytic procedure, alternative to simulation, is described for predicting the transient current response to any applied potential signal under a wide variety of voltammetric conditions. Diverse geometries may be treated; the electrode reaction may have any degree of reversibility; homogeneous chemical reactions may be involved. Conceptually, the method consists of splitting the overall problem into three components, each of which is solved separately. Examples presented include...[Show more]

dc.contributor.authorMahon, Peter
dc.contributor.authorMyland, Jan
dc.contributor.authorOldham, Keith
dc.date.accessioned2015-12-13T22:22:37Z
dc.identifier.issn0022-0728
dc.identifier.urihttp://hdl.handle.net/1885/72329
dc.description.abstractA modular semianalytic procedure, alternative to simulation, is described for predicting the transient current response to any applied potential signal under a wide variety of voltammetric conditions. Diverse geometries may be treated; the electrode reaction may have any degree of reversibility; homogeneous chemical reactions may be involved. Conceptually, the method consists of splitting the overall problem into three components, each of which is solved separately. Examples presented include cyclic voltammetry and (Osteryoung) square-wave voltammetry.
dc.publisherElsevier
dc.sourceJournal of Electroanalytical Chemistry
dc.subjectKeywords: Chemical reactions; Computer simulation; Convolution; Cyclic voltammetry; Electric currents; Electrodes; Square-wave voltammetry; Electrochemistry Convolution; Modelling; Voltammetry
dc.titleA fresh approach to voltammetric modelling.
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume537
dc.date.issued2002
local.identifier.absfor030604 - Electrochemistry
local.identifier.ariespublicationMigratedxPub3192
local.type.statusPublished Version
local.contributor.affiliationMahon, Peter, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMyland, Jan, Trent University
local.contributor.affiliationOldham, Keith, Trent University
local.description.embargo2037-12-31
local.bibliographicCitation.startpage1
local.bibliographicCitation.lastpage5
local.identifier.doi10.1016/S0022-0728(02)01263-9
dc.date.updated2015-12-11T07:57:30Z
local.identifier.scopusID2-s2.0-0037195430
CollectionsANU Research Publications

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