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Structure and magnetism of heptanuclear complexes formed on encapsulation of hexacyanoferrate(II) with the Mn(II) and Ni(II) complexes of 1,4-Bis(2-pyridylmethyl)-1,4,7-triazacyclononane.

Parker, Richard; Spiccia, Leone; Moubaraki, Boujemaa; Murray, Keith; Hockless, David; Rae, A David; Willis, Anthony


The reaction of [Mn(dmptacn)OH2]2+ and [Ni(dmptacn)OH2]2+ (dmptacn = 1,4-bis(2-pyridylmethyl)-1,4,7-triazacyclononane) with each cyano ligand on ferricyanide results in the assembly of heteropolynuclear cations around the cyanometalate core and reduction

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic010711d


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