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Synthesis, magnetic properties, and phosphoesterase activity of dinuclear cobalt(II) complexes

Daumann, Lena J; Comba, Peter; Larrabee, James A; Schenk, Gerhard; Stranger, Robert; Cavigliasso, German; Gahan, Lawrence


A series of dinuclear cobalt(II) complexes has been prepared and characterized to generate functional and spectroscopic models for cobalt(II) substituted phosphoesterase enzymes such as the potential bioremediator GpdQ. Reaction of ligands based on 2,2'-(((2-hydroxy-5-methyl-1,3-phenylene) bis(methylene))bis((pyridin-2-ylmethyl)azanediyl)))diethanol (L1) and 2,6-bis(((2-methoxyethyl)(pyridin-2-ylmethyl)amino)methyl)-4-methylphenol (L2) with cobalt(II) salts afforded [Co2(CO2EtH...[Show more]

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic302418x


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