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Hydrothermal synthesis, structure investigation, and oxide ion conductivity of mixed Si/Ge-based apatite-type phases

Li, Henan; Baikie, Tom; Pramana, Stevin S; Shin, J F; Keenan, Philip; Slater, Peter R; Brink, Frank; Hester, James; An, Tao; White, Tim

Description

Apatite-type oxides ([AI 4][AII 6][(BO4)6]O2), particularly those of the rare-earth silicate and germanate systems, are among the more promising materials being considered as alternative solid oxide fuel cell electrolytes. Nonstoichiometric lanthanum silicate and germanate apatites display pure ionic conductivities exceeding those of yttria-stabilized zirconia at moderate temperatures (500-700 °C). In this study, mixed Si/Ge-based apatites were prepared by hydrothermal synthesis under mild...[Show more]

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
URI: http://hdl.handle.net/1885/70735
Source: Inorganic Chemistry
DOI: 10.1021/ic402370e

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