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From toluene to triquinanes: Formal total syntheses of the sesquiterpenoid natural products (-)-hypnophilin and (-)-coriolin

Bon, David J.-Y. D; Banwell, Martin; Ward, James; Willis, Anthony

Description

The enantiomerically pure cis-1,2-dihydrocatechol 6, which is readily obtained via the whole-cell biotransformation of toluene, has been converted into the linear triquinane 3 using a reaction sequence involving Diels-Alder cycloaddition and oxa-di-π-met

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
URI: http://hdl.handle.net/1885/69939
Source: Tetrahedron
DOI: 10.1016/j.tet.2012.11.069

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