A continuum solvent model of the partial molar volumes and entropies of ionic solvation
Continuum solvent models of electrolyte solutions are extremely useful. However, before we can use them with confidence, it is important to test them by comparison with a range of experimental properties. Here, we have adapted our recently developed1,2 simple continuum solvent model of ionic solvation free energies to calculate the solvation entropies and partial molar volumes of a group of monovalent and monatomic ions. This procedure gives good quantitative agreement for larger ions, and...[Show more]
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|Source:||Journal of Physical Chemistry B|
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