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Surface Tension of Electrolytes: Specific Ion Effects Explained by Dispersion Forces

Bostrom, Mathias; Williams, David; Ninham, Barry

Description

The surface tension of ionic solutions shows marked specific ion effects not explained by existing theories. The effects are here accounted for by invoking a dispersion force between ions and the air-water interface. The measurements can be explained with reasonable values for the dispersion potential.

dc.contributor.authorBostrom, Mathias
dc.contributor.authorWilliams, David
dc.contributor.authorNinham, Barry
dc.date.accessioned2015-12-10T23:34:32Z
dc.identifier.issn0743-7463
dc.identifier.urihttp://hdl.handle.net/1885/69462
dc.description.abstractThe surface tension of ionic solutions shows marked specific ion effects not explained by existing theories. The effects are here accounted for by invoking a dispersion force between ions and the air-water interface. The measurements can be explained with reasonable values for the dispersion potential.
dc.publisherAmerican Chemical Society
dc.sourceLangmuir
dc.subjectKeywords: Dispersion forces; Dispersions; Ions; Phase interfaces; Solutions; Surface tension; Electrolytes
dc.titleSurface Tension of Electrolytes: Specific Ion Effects Explained by Dispersion Forces
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume17
dc.date.issued2001
local.identifier.absfor030603 - Colloid and Surface Chemistry
local.identifier.ariespublicationMigratedxPub2028
local.type.statusPublished Version
local.contributor.affiliationBostrom, Mathias, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWilliams, David, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationNinham, Barry, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.startpage4475
local.bibliographicCitation.lastpage4478
local.identifier.doi10.1021/la0102298
dc.date.updated2015-12-10T11:34:07Z
local.identifier.scopusID2-s2.0-0035943181
CollectionsANU Research Publications

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