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Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores

Chen, Bin; Eddaoudi, M; Hyde, Stephen; O'Keeffe, Michael; Yaghi, O

Description

Interpenetration (catenation) has long been considered a major impediment in the achievement of stable and porous crystalline structures. A strategy for the design of highly porous and structurally stable networks makes use of metal organic building blocks that can be assembled on a triply periodic P-minimal geometric surface to produce structures that are interpenetrating - more accurately considered as interwoven. We used 4,4′,4″-benzene-1,3,5-triyl-tribenzoic acid (H3BTB), copper(II)...[Show more]

dc.contributor.authorChen, Bin
dc.contributor.authorEddaoudi, M
dc.contributor.authorHyde, Stephen
dc.contributor.authorO'Keeffe, Michael
dc.contributor.authorYaghi, O
dc.date.accessioned2015-12-10T23:34:21Z
dc.identifier.issn0036-8075
dc.identifier.urihttp://hdl.handle.net/1885/69402
dc.description.abstractInterpenetration (catenation) has long been considered a major impediment in the achievement of stable and porous crystalline structures. A strategy for the design of highly porous and structurally stable networks makes use of metal organic building blocks that can be assembled on a triply periodic P-minimal geometric surface to produce structures that are interpenetrating - more accurately considered as interwoven. We used 4,4′,4″-benzene-1,3,5-triyl-tribenzoic acid (H3BTB), copper(II) nitrate, and N,N′-dimethylformamide (DMF) to prepare Cu3(BTB)2(H2O)3 · (DMF)9(H2O)2 (MOF-14), whose structure reveals a pair of interwoven metal-organic frameworks that are mutually reinforced. The structure contains remarkably large pores, 16.4 angstroms in diameter, in which voluminous amounts of gases and organic solvents can be reversibly sorbed.
dc.publisherAmerican Association for the Advancement of Science
dc.sourceScience
dc.subjectKeywords: benzoic acid derivative; copper derivative; metal; n,n dimethylformamide; organic compound; adsorption; article; chemical composition; crystal structure; crystallization; molecular interaction; molecular stability; porosity; priority journal
dc.titleInterwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume291
dc.date.issued2001
local.identifier.absfor020204 - Plasma Physics; Fusion Plasmas; Electrical Discharges
local.identifier.ariespublicationMigratedxPub2012
local.type.statusPublished Version
local.contributor.affiliationChen, Bin, Hangzhou Teachers College
local.contributor.affiliationEddaoudi, M, University of Michigan
local.contributor.affiliationHyde, Stephen, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationO'Keeffe, M, Arizona State University
local.contributor.affiliationYaghi, O, University of Michigan
local.description.embargo2037-12-31
local.bibliographicCitation.issue9 February 2001
local.bibliographicCitation.startpage1021
local.bibliographicCitation.lastpage1023
local.identifier.doi10.1126/science.1056598
dc.date.updated2015-12-10T11:32:33Z
local.identifier.scopusID2-s2.0-0035132505
CollectionsANU Research Publications

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