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Syntheses and spectroscopic, structural, electrochemical, spectroelectrochemical, and theoretical studies of osmium(II) mono- and bis-alkynyl complexes

West, Patrick; Cifuentes, Marie; Schwich, Torsten; Randles , Michael; Morrall, Joseph; Kulasekera, Erandi; Petrie, Simon; Stranger, Robert; Humphrey, Mark


The syntheses of trans-[Os(C≡C-4-C6H4X)Cl(dppe)2] [X = Br (3), I (4)], trans-[Os(C≡C-4-C6H4X)(NH3)(dppe)2](PF6) [X = H (5(PF6)), I (6(PF6))], and trans-[Os(C≡C-4-C6H4X)(C≡C-4-C6H4Y)(dppe)2] [X = Y = H (7), X = I, Y = C≡CSiPri3 (8)] are reported,

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic202542c


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