Syntheses and spectroscopic, structural, electrochemical, spectroelectrochemical, and theoretical studies of osmium(II) mono- and bis-alkynyl complexes

West, Patrick; Cifuentes, Marie; Schwich, Torsten; Randles , Michael; Morrall, Joseph; Kulasekera, Erandi; Petrie, Simon; Stranger, Robert; Humphrey, Mark

doi:10.1021/ic202542c

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Syntheses and spectroscopic, structural, electrochemical, spectroelectrochemical, and theoretical studies of osmium(II) mono- and bis-alkynyl complexes

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West, Patrick; Cifuentes, Marie; Schwich, Torsten; Randles , Michael; Morrall, Joseph; Kulasekera, Erandi; Petrie, Simon; Stranger, Robert; Humphrey, Mark

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The syntheses of trans-[Os(C≡C-4-C6H4X)Cl(dppe)2] [X = Br (3), I (4)], trans-[Os(C≡C-4-C6H4X)(NH3)(dppe)2](PF6) [X = H (5(PF6)), I (6(PF6))], and trans-[Os(C≡C-4-C6H4X)(C≡C-4-C6H4Y)(dppe)2] [X = Y = H (7), X = I, Y = C≡CSiPri3 (8)] are reported,

Collections	ANU Research Publications
Date published:	2012
Type:	Journal article
URI:	http://hdl.handle.net/1885/68352
Source:	Inorganic Chemistry
DOI:	10.1021/ic202542c

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Syntheses and spectroscopic, structural, electrochemical, spectroelectrochemical, and theoretical studies of osmium(II) mono- and bis-alkynyl complexes

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