Skip navigation
Skip navigation

Syntheses, structural, electrochemical and optical studies of heterobinuclear ruthenium-osmium alkynyl complexes

West, Patrick; Schwich, Torsten; Cifuentes, Marie; Humphrey, Mark

Description

The complexes trans-[Os(CCC6H4-4-CCR)Cl(dppe)2] (R = SiPri3 1, H 2), trans,trans-[(dppe)2ClOs(CCC6H4-4-CC)RuX(dppe)2] (X = Cl 3, CCC6H4-4-CCSiPri3 4), trans-[Os(CCC6H4-4-CCC6H4-4-CCR) Cl(dppe)2] (R = SiPri3 5, H 6), and trans,trans-[(dppe)2ClOs(CCC6H4-4-CCC6H4-4-CC)RuCl(dppe)2] (7) have been synthesized, and the identities of 1, 2, and 6 confirmed by single-crystal X-ray diffraction studies. Cyclic voltammetry shows that the mononuclear complexes 1, 2, 5, and 6 are oxidized at potentials within...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/68056
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2011.02.013

Download

File Description SizeFormat Image
01_West_Syntheses,_structural,_2011.pdf852.28 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  12 November 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator