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Syntheses, structural, electrochemical and optical studies of heterobinuclear ruthenium-osmium alkynyl complexes

West, Patrick; Schwich, Torsten; Cifuentes, Marie; Humphrey, Mark


The complexes trans-[Os(CCC6H4-4-CCR)Cl(dppe)2] (R = SiPri3 1, H 2), trans,trans-[(dppe)2ClOs(CCC6H4-4-CC)RuX(dppe)2] (X = Cl 3, CCC6H4-4-CCSiPri3 4), trans-[Os(CCC6H4-4-CCC6H4-4-CCR) Cl(dppe)2] (R = SiPri3 5, H 6), and trans,trans-[(dppe)2ClOs(CCC6H4-4-CCC6H4-4-CC)RuCl(dppe)2] (7) have been synthesized, and the identities of 1, 2, and 6 confirmed by single-crystal X-ray diffraction studies. Cyclic voltammetry shows that the mononuclear complexes 1, 2, 5, and 6 are oxidized at potentials within...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2011.02.013


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