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Isolation of thuridillins D-F, Diterpene Metabolites from the Australian Sacoglossan Mollusk Thuridilla splendens ; Relative configuration of the Epoxylactone Ring

Somerville, Michael J; Katavic, Peter L; Lambert, Lynette K; Pierens, Gregory K; Blanchfield , Joanne Therese; Cimino, Guido; Mollo, Ernesto; Gavagnin, Margherita; Banwell, Martin; Garson, Mary J


This first chemical study of the sacoglossan mollusk Thuridilla splendens from Mooloolaba, South East Queensland, has resulted in the isolation of three new metabolites, thuridillins D-F (1-3), and one known metabolite, thuridillin A (4). Thuridillin D (1) was isolated by conventional flash chromatography on silica gel, while a mixture of thuridillins E (2) and F (3) was obtained by PTLC on AgNO3-impregnated silica gel. Thuridillins D-F were determined to be structurally related to thuridillin...[Show more]

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: Journal of Natural Products
DOI: 10.1021/np300442s


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