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Applications of X-ray absorption spectroscopy to biologically relevant metal-based chemistry

Best, Stephen Peter; Cheah, Michael


Recent developments in the understanding of the biosynthesis of the active site of the nitrogenase enzyme, the structure of the iron centre of [Fe]-hydrogenase and the structure and biomimetic chemistry of the [FeFe] hydrogenase H-cluster as deduced by application of X-ray spectroscopy are reviewed. The techniques central to this work include X-ray absorption spectroscopy either in the form of extended X-ray absorption fine structure (EXAFS), X-ray absorption near-edge structure (XANES) and...[Show more]

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Radiation Physics and Chemistry
DOI: 10.1016/j.radphyschem.2009.03.072


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