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Magnetic and mechanical anisotropy in a manganese 2-methylsuccinate framework structure

Li, Wei; Barton, Phillip T.; Mangalampalli, S.R.N. Kiran; Burwood, Ryan P.; Ramamurty, U; Cheetham, A


Hybrid inorganic-organic framework materials exhibit unique properties that can be advantageously tuned through choice of the inorganic and organic components and by control of the crystal structure. We present a new hydrothermally prepared 3D hybrid framework, [Mn(2-methylsuccinate)]n (1), comprising alternating 2D manganese oxide sheets and isolated MnO6 octahedra, pillared via syn, anti-syn carboxylates. Powder magnetic characterization shows that the compound is a homospin MnII ferrimagnet...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Chemistry, A European Journal
DOI: 10.1002/chem.201101251


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