XAFS and DFT characterisation of protonated reduced fe hydrogenase analogues and their implications for electrocatalytic proton reduction
The relationship between the structures of reduced, protonated diiron compounds relevant to the diiron subsite of the Fe-hydrogenase H cluster, [2Fe]H, and the rate of electrocatalytic proton reduction is explored by a combination of experimental and computational approaches. Analysis of the X-ray absorption fine structure (XAFS) of the two-electron, twoproton product of [Fe(CO)3]2(μ-PPh2)2 (DP) shows distortions of the primary coordination environment of the Fe centre that result from the...[Show more]
|Collections||ANU Research Publications|
|Source:||European Journal of Inorganic Chemistry|
|01_Cheah_XAFS_and_DFT_characterisation_2011.pdf||748.6 kB||Adobe PDF||Request a copy|
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.