Skip navigation
Skip navigation

Pressure-Induced Bond Rearrangement and Reversible Phase Transformation in a Metal-Organic Framework

Spencer, Elinor C; Mangalampalli, S.R.N. Kiran; Li, Wei; Ramamurty, U; Ross, Nancy; Cheetham, Anthony K


Pressure-induced phase transformations (PIPTs) occur in a wide range of materials. In general, the bonding characteristics, before and after the PIPT, remain invariant in most materials, and the bond rearrangement is usually irreversible due to the strain induced under pressure. A reversible PIPT associated with a substantial bond rearrangement has been found in a metal-organic framework material, namely [tmenH2][Er(HCOO) 4]2 (tmenH2 2+=N,N,N',N'- tetramethylethylenediammonium). The transition...[Show more]

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
Source: Angewandte Chemie International Edition
DOI: 10.1002/anie.201310276


File Description SizeFormat Image
01_Spencer_Pressure-Induced_Bond_2014.pdf899.85 kBAdobe PDF    Request a copy

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  17 November 2022/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator