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Triphenylamine derivatized phenylacetylene macrocycle with large two-photon absorption cross-section

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Fang, Zhen; Samoc, Marek; Webster, Richard D; Samoc, Anna; Lai, Yee-Hing

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A phenylacetylene macrocycle (PAM) derivative containing triphenylamine as the framework was synthesized in one-step Sonogashira coupling. The photophysical and electrochemical properties were investigated in details. This hexamer shows significant enhancement in two-photon absorption cross-section relative to reported PAM derivatives.

dc.contributor.authorFang, Zhen
dc.contributor.authorSamoc, Marek
dc.contributor.authorWebster, Richard D
dc.contributor.authorSamoc, Anna
dc.contributor.authorLai, Yee-Hing
dc.date.accessioned2015-12-10T23:18:03Z
dc.identifier.issn0040-4039
dc.identifier.urihttp://hdl.handle.net/1885/65453
dc.description.abstractA phenylacetylene macrocycle (PAM) derivative containing triphenylamine as the framework was synthesized in one-step Sonogashira coupling. The photophysical and electrochemical properties were investigated in details. This hexamer shows significant enhancement in two-photon absorption cross-section relative to reported PAM derivatives.
dc.publisherElsevier
dc.sourceTetrahedron Letters
dc.subjectKeywords: aniline derivative; macrocyclic compound; phenylacetylene; absorption; article; cyclic potentiometry; electrochemistry; light absorption; oxidation; Sonogashira reaction; synthesis Electrochemistry; One-step; Phenylacetylene macrocycle; Triphenylamine; Two-photon absorption
dc.titleTriphenylamine derivatized phenylacetylene macrocycle with large two-photon absorption cross-section
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume53
dc.date.issued2012
local.identifier.absfor030500 - ORGANIC CHEMISTRY
local.identifier.ariespublicationf5625xPUB1108
local.type.statusPublished Version
local.contributor.affiliationFang, Zhen, National University of Singapore
local.contributor.affiliationSamoc, Marek, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWebster, Richard D, Nanyang Technological University
local.contributor.affiliationSamoc, Anna, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLai, Yee-Hing, National University of Singapore
local.description.embargo2037-12-31
local.bibliographicCitation.issue36
local.bibliographicCitation.startpage4885
local.bibliographicCitation.lastpage4888
local.identifier.doi10.1016/j.tetlet.2012.07.003
dc.date.updated2016-02-24T08:37:51Z
local.identifier.scopusID2-s2.0-84864423758
local.identifier.thomsonID000307491200023
CollectionsANU Research Publications

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