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Homoleptic cerium(III) and cerium(IV) nitroxide complexes: Significant stabilization of the 4+ oxidation state

Bogart, Justin A.; Lewis, Andrea J.; Medling, Scott; Piro, Nicholas A.; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

Description

Electrochemical experiments performed on the complex CeIV[2- (tBuNO)py]4, where [2-(tBuNO)py]- = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [nBu4N] 2[Ce(NO3)6] in acetonitrile and a 2.95

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
URI: http://hdl.handle.net/1885/64912
Source: Inorganic Chemistry
DOI: 10.1021/ic401974t

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