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Experimental evidence for competitive N-O and O-C bond homolysis in gas-phase alkoxyamines

Marshall, David L; Gryn'ova, Ganna; Coote, Michelle; Barker, Philip J.; Blanksby, Stephen James


The extensive use of alkoxyamines in controlled radical polymerisation and polymer stabilisation is based on rapid cycling between the alkoxyamine (R1R2NOR3) and a stable nitroxyl radical (R1R2NO•) via homolysis of the labile OC bond. Competing homolysi

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: International Journal of Mass Spectrometry
DOI: 10.1016/j.ijms.2014.06.030


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