Experimental evidence for competitive N-O and O-C bond homolysis in gas-phase alkoxyamines
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Marshall, David L; Gryn'ova, Ganna; Coote, Michelle; Barker, Philip J.; Blanksby, Stephen James
Description
The extensive use of alkoxyamines in controlled radical polymerisation and polymer stabilisation is based on rapid cycling between the alkoxyamine (R1R2NOR3) and a stable nitroxyl radical (R1R2NO•) via homolysis of the labile OC bond. Competing homolysi
| Collections | ANU Research Publications |
|---|---|
| Date published: | 2015 |
| Type: | Journal article |
| URI: | http://hdl.handle.net/1885/64313 |
| Source: | International Journal of Mass Spectrometry |
| DOI: | 10.1016/j.ijms.2014.06.030 |
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| File | Description | Size | Format | Image |
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| 01_Marshall_Experimental_evidence_for_2015.pdf | 628.06 kB | Adobe PDF |  |
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