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Selenoxopropadienylidene (CCCSe) as a Bridging Ligand

Hill, Anthony; Manzano, Richard; Sharma, Manab; Ward, James


The reaction of [W(≡CC≡CSiMe3)(CO)2(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [nBu4N]F and selenium in the presence of [RuCl(PPh3)2(η-C5H5)] affords a mixture of the tricarbido complex [WRu(μ-CCC)(CO)2(PPh3)2(η-C5H5)(Tp∗)]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Organometallics
DOI: 10.1021/om5011534


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