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Secondary phosphinocarbyne and phosphaisonitrile complexes

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Colebatch, Annie; Hill, Anthony

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The palladium-mediated reaction of [W(≡CBr)(CO)2(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with primary phosphines PH2R (R = Ph, Cy) affords the secondary phosphinocarbyne complexes [W(≡CPHR)(CO)2(Tp∗)], deprotonation of which prov

dc.contributor.authorColebatch, Annie
dc.contributor.authorHill, Anthony
dc.date.accessioned2015-12-10T23:11:56Z
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/1885/63900
dc.description.abstractThe palladium-mediated reaction of [W(≡CBr)(CO)2(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with primary phosphines PH2R (R = Ph, Cy) affords the secondary phosphinocarbyne complexes [W(≡CPHR)(CO)2(Tp∗)], deprotonation of which prov
dc.publisherAmerican Chemical Society
dc.sourceJournal of the American Chemical Society
dc.titleSecondary phosphinocarbyne and phosphaisonitrile complexes
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume136
dc.date.issued2014
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4005981xPUB861
local.type.statusPublished Version
local.contributor.affiliationColebatch, Annie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue50
local.bibliographicCitation.startpage17442
local.bibliographicCitation.lastpage17445
local.identifier.doi10.1021/ja511308k
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2015-12-10T09:25:15Z
local.identifier.scopusID2-s2.0-84919359789
local.identifier.thomsonID000346682600022
CollectionsANU Research Publications

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