Secondary phosphinocarbyne and phosphaisonitrile complexes
The palladium-mediated reaction of [W(≡CBr)(CO)2(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with primary phosphines PH2R (R = Ph, Cy) affords the secondary phosphinocarbyne complexes [W(≡CPHR)(CO)2(Tp∗)], deprotonation of which prov
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