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Secondary phosphinocarbyne and phosphaisonitrile complexes

Colebatch, Annie; Hill, Anthony


The palladium-mediated reaction of [W(≡CBr)(CO)2(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with primary phosphines PH2R (R = Ph, Cy) affords the secondary phosphinocarbyne complexes [W(≡CPHR)(CO)2(Tp∗)], deprotonation of which prov

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja511308k


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