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Crystal structure of ( E )-1-(4- tert -butyl-phen-yl)-2-(4-iodo-phen-yl)ethene.

Chen, Zhiwei; Moxey, Graeme

Description

The title compound, C<inf>18</inf>H<inf>19</inf>I, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the bridging C=C bond. They differ in the orientation of the two benzene rings; the dihedral angle being 12.3 (5)° in molecule A, but only 1.0 (6)° in molecule B. In the crystal, the individual molecules are linked by C - I⋯π interactions forming zigzag A and zigzag B chains propagating along [001]. The structure was refined...[Show more]

dc.contributor.authorChen, Zhiwei
dc.contributor.authorMoxey, Graeme
dc.date.accessioned2015-12-10T23:11:19Z
dc.identifier.issn1600-5368
dc.identifier.urihttp://hdl.handle.net/1885/63764
dc.description.abstractThe title compound, C<inf>18</inf>H<inf>19</inf>I, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the bridging C=C bond. They differ in the orientation of the two benzene rings; the dihedral angle being 12.3 (5)° in molecule A, but only 1.0 (6)° in molecule B. In the crystal, the individual molecules are linked by C - I⋯π interactions forming zigzag A and zigzag B chains propagating along [001]. The structure was refined as an inversion twin [Flack parameter = 0.48 (2)].
dc.publisherMunksgaard International Publishers
dc.rightsAuthor/s retain copyright
dc.sourceActa Crystallographica Section E: Structure Reports Online
dc.titleCrystal structure of ( E )-1-(4- tert -butyl-phen-yl)-2-(4-iodo-phen-yl)ethene.
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume71
dc.date.issued2015
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationU4217927xPUB845
local.type.statusPublished Version
local.contributor.affiliationChen, Zhiwei, Jiangnan University
local.contributor.affiliationMoxey, Graeme, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.issue5
local.bibliographicCitation.startpageo309
local.bibliographicCitation.lastpage10
local.identifier.doi10.1107/S2056989015007185
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2015-12-10T09:21:32Z
local.identifier.scopusID2-s2.0-84928154321
dcterms.accessRightsOpen Access
CollectionsANU Research Publications

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