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Synthesis and Reactivity of Phosphinocarbyne Complexes

Colebatch, Annie; Hill, Anthony; Sharma, Manab

Description

The successive treatment of [W(≡CBr)(CO)2(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with nBuLi and ClPPh2 affords the phosphinocarbyne complex [W(≡CPPh2)(CO)2(Tp∗)] (1), DFT interrogation

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
URI: http://hdl.handle.net/1885/63660
Source: Organometallics
DOI: 10.1021/om500833n

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