Synthesis of a D-ring Isomer of Galanthamine via a Radical-Based Smiles Rearrangement Reaction
The 1,9-ethanoiminomethano-bridged tetrahydrodibenzo[b,d]-furan 2, a non-natural isomer of the alkaloid (-)-galanthamine (1) varying in the manner in which the D-ring is annulated to the ABC-core, has been prepared in racemic form. The synthetic sequence
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|Source:||Journal of Organic Chemistry|
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