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Synthesis of a D-ring Isomer of Galanthamine via a Radical-Based Smiles Rearrangement Reaction

Lan, Ping; Jackson, Colin; Banwell, Martin; Willis, Anthony

Description

The 1,9-ethanoiminomethano-bridged tetrahydrodibenzo[b,d]-furan 2, a non-natural isomer of the alkaloid (-)-galanthamine (1) varying in the manner in which the D-ring is annulated to the ABC-core, has been prepared in racemic form. The synthetic sequence

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
URI: http://hdl.handle.net/1885/63560
Source: Journal of Organic Chemistry
DOI: 10.1021/jo501255c

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