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ortho -Metallated triphenylphosphine chalcogenide complexes of platinum and palladium: synthesis and catalytic activity

Priver, Steven H; Bennett, Martin; Willis, Anthony; Pottabathula, Srinivas; Lakshmi Kantam, Mannepalli; Bhargava, Suresh Kumar

Description

Treatment of [PtI2(COD)] (COD = 1,5-cyclooctadiene) with 2-LiC6H4P(S)Ph2 gives the complex cis-[Pt{κ2-2-C6H4P(S)Ph2} 2] (1) containing a pair of ortho-metallated triphenylphosphine sulfide rings. The selenium counterpart, [Pt{κ2-2-C 6H4P(Se)Ph2}2] (2),

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
URI: http://hdl.handle.net/1885/63544
Source: Dalton Transactions
DOI: 10.1039/c4dt01236d

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