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An analytical data inversion method for magnetic circular dichroism spectra dominated by the "B-term"

Reimers, Jeffrey R; Krausz, Elmars

Description

A simple procedure is developed enabling the analytical inversion of an (unpolarized) absorption spectrum combined with a Magnetic Circular Dichroism (MCD) spectrum to resolve two overlapping bands of orthogonal polarization. This method is appropriate when (i) the overlapping transitions are well isolated from other bands, and (ii) when their electronic spacing is large enough so that the "A-term" and "C-term" contributions to the MCD spectrum can be ignored and hence only the "B-term"...[Show more]

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
URI: http://hdl.handle.net/1885/63422
Source: Physical Chemistry Chemical Physics
DOI: 10.1039/C3CP53730G

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