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Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity

Bolte, Benoit; Gagosz, Fabien


A series of allenyl ethers can be transformed into various fused or spiro tetrahydrofurans and tetrahydropyrans following a hydride shift/cyclization sequence. A divergence in product selectivity, which depends on the nature of the catalyst used (Au(I) complex or Brønsted acid), was observed.

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja202336p


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