Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity
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Description
A series of allenyl ethers can be transformed into various fused or spiro tetrahydrofurans and tetrahydropyrans following a hydride shift/cyclization sequence. A divergence in product selectivity, which depends on the nature of the catalyst used (Au(I) complex or Brønsted acid), was observed.
| Collections | ANU Research Publications |
|---|---|
| Date published: | 2011 |
| Type: | Journal article |
| URI: | http://hdl.handle.net/1885/63347 |
| Source: | Journal of the American Chemical Society |
| DOI: | 10.1021/ja202336p |
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| File | Description | Size | Format | Image |
|---|---|---|---|---|
| 01_Bolte_Gold_and_Brønsted_Acid_2011.pdf | 2.64 MB | Adobe PDF | Request a copy |
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