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Stereoselective aggregation of chiral complexes with threefold-symmetric pendant carboxyl groups: an example of "perfect" self-assembly not seen in the crystalline state?

Fischer, Janina; Hall, Jeremy; Patty, Philipus J.; Williams, Martin A. K.; Waterland, Mark R.; Telfer, Shane G.


The self-assembly of tris(bidentate) chiral complexes, [M(4- carboxyphenyldipyrrinato)3] (M = Co(iii), Rh(iii)), with a threefold-symmetric array of peripheral carboxyl groups is detailed. Thin sheet-like aggregates are observed in methanol/water mixtures

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: RSC Advances
DOI: 10.1039/c3ra41234b


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