Dihydroperimidine-derived PNP pincer complexes as intermediates en route to N-heterocyclic carbene pincer complexes

Hill, Anthony; McQueen, Caitlin

doi:10.1021/om5000985

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Dihydroperimidine-derived PNP pincer complexes as intermediates en route to N-heterocyclic carbene pincer complexes

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Hill, Anthony; McQueen, Caitlin

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The reaction of N,N′-bis(dicyclohexylphosphinomethyl) dihydroperimidine (H2C(NCH2PCy2) 2C10H6-1,8, 1a) with [RuCl2(PPh 3)3] in THF affords the perimidinylidene-based N-heterocyclic carbene (per-NHC) pincer complex [RuCl2(OC 4H8){=C(NCH2PCy2)2C 10H6}] (2

Collections	ANU Research Publications
Date published:	2014
Type:	Journal article
URI:	http://hdl.handle.net/1885/63113
Source:	Organometallics
DOI:	10.1021/om5000985

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Dihydroperimidine-derived PNP pincer complexes as intermediates en route to N-heterocyclic carbene pincer complexes

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