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A golden ring: molecular gold carbido complexes

Borren, Elliot; Hill, Anthony; Shang, Rong; Sharma, Manab; Willis, Anthony

Description

Stannylcarbynes [M(≡CSnMe3)(CO)2(Tp*)] [M = Mo, W; Tp* = hydrotris(dimethylpyrazol-1-yl)borate], which are readily obtained via the successive treatment of [M(≡CBr)(CO) 2(Tp*)] with nBuLi and ClSnMe3, serve as effective carbyne transmetalation agents

dc.contributor.authorBorren, Elliot
dc.contributor.authorHill, Anthony
dc.contributor.authorShang, Rong
dc.contributor.authorSharma, Manab
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-10T23:07:50Z
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/1885/63029
dc.description.abstractStannylcarbynes [M(≡CSnMe3)(CO)2(Tp*)] [M = Mo, W; Tp* = hydrotris(dimethylpyrazol-1-yl)borate], which are readily obtained via the successive treatment of [M(≡CBr)(CO) 2(Tp*)] with nBuLi and ClSnMe3, serve as effective carbyne transmetalation agents
dc.publisherAmerican Chemical Society
dc.sourceJournal of the American Chemical Society
dc.subjectKeywords: Carbynes; CBr; Heteronuclear; Tetrameric; Transmetalation; Gold; Tungsten compounds; Gold compounds; barban; boric acid; gold; organometallic compound; palladium; tetramer; tin; article; chemical bond; chemical interaction; chemical structure; complex for
dc.titleA golden ring: molecular gold carbido complexes
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume135
dc.date.issued2013
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationU4217927xPUB762
local.type.statusPublished Version
local.contributor.affiliationBorren, Elliot, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationShang, Rong, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSharma, Manab, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue13
local.bibliographicCitation.startpage4942
local.bibliographicCitation.lastpage4945
local.identifier.doi10.1021/ja400128h
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:45:14Z
local.identifier.scopusID2-s2.0-84875767867
local.identifier.thomsonID000317259300011
CollectionsANU Research Publications

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