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A golden ring: molecular gold carbido complexes

Borren, Elliot; Hill, Anthony; Shang, Rong; Sharma, Manab; Willis, Anthony


Stannylcarbynes [M(≡CSnMe3)(CO)2(Tp*)] [M = Mo, W; Tp* = hydrotris(dimethylpyrazol-1-yl)borate], which are readily obtained via the successive treatment of [M(≡CBr)(CO) 2(Tp*)] with nBuLi and ClSnMe3, serve as effective carbyne transmetalation agents

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja400128h


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