A golden ring: molecular gold carbido complexes
Stannylcarbynes [M(≡CSnMe3)(CO)2(Tp*)] [M = Mo, W; Tp* = hydrotris(dimethylpyrazol-1-yl)borate], which are readily obtained via the successive treatment of [M(≡CBr)(CO) 2(Tp*)] with nBuLi and ClSnMe3, serve as effective carbyne transmetalation agents
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|Source:||Journal of the American Chemical Society|
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