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N-Heterocyclic Silyl Pincer Ligands

Dixon, Lily; Hill, Anthony; Sinha, Arup; Ward, James


The reaction of 1,2-C6H4(NHCH2PPh 2)2 with chlorosilanes Cl2SiHR (R = Ph, Cl) affords the benzosiladiazoles RHSi(NCH2PPh2) 2C6H4 (R = Ph, 1; Cl, 2). The phenyl derivative 1 undergoes chelate-assisted Si-H activation with [RuPhCl(CO)(PPh 3)2] and [RhCl(PPh

CollectionsANU Research Publications
Date published: 2014
Type: Journal article
Source: Organometallics
DOI: 10.1021/om400792j


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