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Heterodinuclear Bridging Carbido and Phosphoniocarbyne Complexes

Hill, Anthony; Sharma, Manab; Willis, Anthony

Description

The sequential treatment of [W(≡CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) withnBuLi and [NiCl2(PEt3)2] initially affords the bridging carbido complex [WNi(μ-C)(CO)2(PEt3)2Cl{HB(pzMe2)3}], which is however unstable and isomerizes cleanly to the bridgin

dc.contributor.authorHill, Anthony
dc.contributor.authorSharma, Manab
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-10T23:06:39Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/62744
dc.description.abstractThe sequential treatment of [W(≡CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) withnBuLi and [NiCl2(PEt3)2] initially affords the bridging carbido complex [WNi(μ-C)(CO)2(PEt3)2Cl{HB(pzMe2)3}], which is however unstable and isomerizes cleanly to the bridgin
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: CBr; Sequential treatments; Tungsten compounds; Chlorine compounds
dc.titleHeterodinuclear Bridging Carbido and Phosphoniocarbyne Complexes
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume31
dc.date.issued2012
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationU4217927xPUB732
local.type.statusPublished Version
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSharma, Manab, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue7
local.bibliographicCitation.startpage2538
local.bibliographicCitation.lastpage2542
local.identifier.doi10.1021/om201057c
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:45:02Z
local.identifier.scopusID2-s2.0-84859588746
local.identifier.thomsonID000303076600007
CollectionsANU Research Publications

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