Thermally reversible Diels-Alder-based polymerization: an experimental and theoretical assessment
A pair of monomers capable of undergoing reversible polymerization - based on reversible Diels-Alder (DA) chemistry - as a function of the applied reaction temperature is presented. Specifically, the reaction of isophorone bis(sorbic carbamate), a difunctional diene, with 1,4-phenylenebis(methylene) bis((diethoxyphosphoryl)methanedithioformate), a difunctional dithioester, was studied in detail. Various factors, including the monomer concentration, the type of solvent, and the presence of a...[Show more]
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