Skip navigation
Skip navigation

Thermally reversible Diels-Alder-based polymerization: an experimental and theoretical assessment

Zhou, Jiawen; Guimard, Nathalie; Inglis, Andrew; Namazian, Mansoor; Lin, Ching-Yeh; Coote, Michelle; Spyrou, Emmanouil; Hilf, Stefan; Schmidt, Friedrich Georg; Barner-Kowollik, Christopher

Description

A pair of monomers capable of undergoing reversible polymerization - based on reversible Diels-Alder (DA) chemistry - as a function of the applied reaction temperature is presented. Specifically, the reaction of isophorone bis(sorbic carbamate), a difunctional diene, with 1,4-phenylenebis(methylene) bis((diethoxyphosphoryl)methanedithioformate), a difunctional dithioester, was studied in detail. Various factors, including the monomer concentration, the type of solvent, and the presence of a...[Show more]

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
URI: http://hdl.handle.net/1885/62679
Source: Polymer Chemistry
DOI: 10.1039/C1PY00356A

Download

File Description SizeFormat Image
01_Zhou_Thermally_reversible_2012.pdf497.04 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  12 November 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator