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Synthesis, reactivity, and some photochemistry of ortho-N,N-dimethylaminomethyl substituted aryl and ferrocenyl pentamethylcyclopentadienyl dicarbonyl iron complexes

Grelaud, Guillaume; Roisnel, Thierry; Dorcet, Vincent; Paul, Frederic; Argouarch, Gilles; Humphrey, Mark

Description

Ortho-lithiated N,N-dimethylaminomethyl ferrocene and benzyldimethylamine react with Cp*Fe(CO)2I to give the new complexes ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H 3)Fe(Cp) and Cp*Fe(CO)2-C6H4(o- CH2NMe2). Access to a wide variety of alkoxy-substituted complexes ((Cp

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
URI: http://hdl.handle.net/1885/62661
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2013.05.031

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