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Rate coefficients for intramolecular homolytic substitution of oxyacyl radicals at selenium

Aitken, Heather; Horvat, Sonia; Schiesser, Carl; Lin, Ching-Yeh; Coote, Michelle

Description

Ab initio and density functional calculations predict that intramolecular homolytic substitution reactions of oxyacyl radicals at the selenium atom in ω-alkylseleno-substituted radicals proceed via mechanisms that do not involve hypervalent intermediates

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
URI: http://hdl.handle.net/1885/62530
Source: International Journal of Chemical Kinetics
DOI: 10.1002/kin.20604

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