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Cross-dimerisation between different cisoid- and transoid-1,3-dienes at a ruthenium(0) centre

Hirano, Masafumi; Inoue, Haruka; Okamoto, Takuya; Ueda, Takao; Komine, Nobuyuki; Komiya, Sanshiro; Wang, Xian-qi; Bennett, Martin


Reaction of [Ru(η4-cisoid-2,3-dimethyl-1,3-butadiene) (η4-1,5-COD)(NCMe)] with 1,3-butadiene gives the chelate bis(allylic)ruthenium(ii) complex supine,prone-[Ru(η3: η3-2,3-dimethylocta-2,6-diene-1,8-diyl)(η4-1, 5-COD)] (supine,prone-2da) in 75% isol

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: New Journal of Chemistry
DOI: 10.1039/c3nj00429e


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