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Revealing model dependencies in "Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study"

Junkers, Thomas; Barner-Kowollik, Christopher; Coote, Michelle


In a recent article (W. Meiser, M. Buback, Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study, Macromol. Rapid Commun. 2011, 18, 1490-1494), it is claimed that evidence is found that unequivocally proves that quantum mechanical calculations assessing the equilibrium constant and fragmentation rate coefficients in dithiobenzoate-mediated reversible addition fragmentation transfer (RAFT) systems are beset with a considerable uncertainty. In the present work, we show that...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Macromolecular Rapid Communications
DOI: 10.1002/marc.201100494


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