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Total syntheses of the coumarin-containing natural products pimpinellin and fraxetin using Au(I)-catalyzed intramolecular hydroarylation (IMHA) chemistry

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Cervi, Aymeric; Aillard, Paul; Hazeri, Nourallah; Petit, Laurent; Chai, Christina; Willis, Anthony; Banwell, Martin

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The title natural products (1 and 2, respectively) have been synthesized by Au(I)-catalyzed intramolecular hydroarylation (IMHA) of the relevant aryl propiolate esters (e.g., 13), which were themselves formed by reaction of the corresponding phenols with

dc.contributor.authorCervi, Aymeric
dc.contributor.authorAillard, Paul
dc.contributor.authorHazeri, Nourallah
dc.contributor.authorPetit, Laurent
dc.contributor.authorChai, Christina
dc.contributor.authorWillis, Anthony
dc.contributor.authorBanwell, Martin
dc.date.accessioned2015-12-10T23:05:41Z
dc.identifier.issn0022-3263
dc.identifier.urihttp://hdl.handle.net/1885/62471
dc.description.abstractThe title natural products (1 and 2, respectively) have been synthesized by Au(I)-catalyzed intramolecular hydroarylation (IMHA) of the relevant aryl propiolate esters (e.g., 13), which were themselves formed by reaction of the corresponding phenols with
dc.publisherAmerican Chemical Society
dc.sourceJournal of Organic Chemistry
dc.subjectKeywords: Dicyclohexylcarbodiimide; Hydroarylation; Natural products; Propiolate esters; Propiolic acid; Total synthesis; Trimethylsilyl; Catalysis; Iodine; 1 (3 dimethylaminopropyl) 3 ethylcarbodiimide; benzofuran derivative; coumarin derivative; fraxetin; gold; n
dc.titleTotal syntheses of the coumarin-containing natural products pimpinellin and fraxetin using Au(I)-catalyzed intramolecular hydroarylation (IMHA) chemistry
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume78
dc.date.issued2013
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationu4005981xPUB702
local.type.statusPublished Version
local.contributor.affiliationCervi, Aymeric, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationAillard, Paul, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHazeri, Nourallah, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPetit, Laurent, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationChai, Christina L. L., National University of Singapore
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBanwell, Martin, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue19
local.bibliographicCitation.startpage9876
local.bibliographicCitation.lastpage9882
local.identifier.doi10.1021/jo401583q
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:25:57Z
local.identifier.scopusID2-s2.0-84885129808
local.identifier.thomsonID000326320100032
CollectionsANU Research Publications

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