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Total syntheses of the coumarin-containing natural products pimpinellin and fraxetin using Au(I)-catalyzed intramolecular hydroarylation (IMHA) chemistry

Cervi, Aymeric; Aillard, Paul; Hazeri, Nourallah; Petit, Laurent; Chai, Christina L. L.; Willis, Anthony; Banwell, Martin


The title natural products (1 and 2, respectively) have been synthesized by Au(I)-catalyzed intramolecular hydroarylation (IMHA) of the relevant aryl propiolate esters (e.g., 13), which were themselves formed by reaction of the corresponding phenols with

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Journal of Organic Chemistry
DOI: 10.1021/jo401583q


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